Publications

JCW Group – Chemistry publications

Recent Papers, Communications and Reviews

  • Sulfur and Phosphorus Oxyacid Radicals, M. Buhl, T. Hutson, A. Missio, J. C. Walton, J. Phys. Chem. A, 2022, 126, 760-771. DOI 10.1021/acs.jpca.1c10455
  • Dissociations of free radicals to generate protons, electrophiles or nucleophiles: role in DNA strand breaks, John C. Walton, Chemical Society Reviews, 2021, 50, 7496-7512.  DOI: 10.1039/D1CS00193K
  • EPR Studies on the Addition of Ligated Boryl Radicals to Carbonyl Compounds, John C. Walton, Wen Dai, and Dennis P. Curran, J. Org. Chem. 2020, 85, 4248-4255, doi.org/10.1021/acs.joc.9b03420.
  • Free Radical Mediated Oxidative Degradation of Carotenes and Xanthophylls, Raphael C. Mordi, Olabisi T. Ademosun, Christiana O. Ajanaku, Ifedolapo O. Olanrewaju and John C. Walton, Molecules, 2020, 25, 1038; doi:10.3390/molecules25051038.
  • Radical-Stimulated Nucleophile Release. John C. Walton, J. Org. Chem. 2019, 84, 12606-12616.  DOI:10.1021/acs.joc.9b02159.
  • EPR and Preparative Studies of 5-endo Cyclizations of Radicals Derived from Alkenyl NHC-Boranes Bearing tert-Butyl Ester Substituents. Wen Dai, Dennis P. Curran and John C. Walton, J. Org. Chem., 2019, 84, 2102–2111; DOI: 10.1021/acs.joc.8b03112.
  • 5-Endo Cyclizations of NHC-Boraallyl Radicals Bearing Ester Substituents: Characterization of Derived 1,2-Oxaborole Radicals and Boralactones. Wen Dai, Timothy R. McFadden, Dennis P. Curran, Herbert A. Früchtl and John C. Walton, J. Am. Chem. Soc. 2018, 140, 15868−15875; DOI: 10.1021/jacs.8b09288.
  • Reflex Carbocation Release from Covalent Molecules by Endogenous Free Radicals. John C. Walton, ACS Omega, 2018, 3, 13290-13297; DOI: 10.1021/acsomega.8b02307.
  • Microhydration and the Enhanced Acidity of Free Radicals. John C. Walton, Molecules, 2018, 23, 423; DOI:10.3390/molecules23020423.
  • Enhanced Proton Loss from Neutral Free Radicals: Toward Carbon-Centered Superacids. John C. Walton, J. Phys. Chem. A, 2018, 122, 1422-1431; DOI: 10.1021/acs.jpca.7b11796
  • Dealkanative Main Group Couplings across the peri-Gap. L. J. Taylor, M. Buehl, B. A. Chalmers, M. J. Ray, Piotr Wawrzyniak, J. C. Walton, D. B. Cordes, A. M. Z. Slawin, J. D. Woollins, and P. Kilian, J. Am. Chem. Soc. 2017, 139, 18545?18551; DOI: 10.1021/jacs.7b08682.
  • Generation and Structure of Unique Boriranyl Radicals. J. C. Walton, T. R. McFadden and D. P. Curran, J. Am. Chem. Soc. 2017, 139, 16514-16517; DOI: 10.1021/jacs.7b10788.
  • N- to C-Sulfonyl Photoisomerisation of Dihydropyridinones: a Synthetic and Mechanistic Study. P.-P. Yeh, J. E. Taylor, D. G. Stark, D. S. B. Daniels, C. Fallan, J. C. Walton and A. D. Smith, Org. Biomol. Chem. 2017, 15, 8914 – 8922; DOI: 10.1039/c7ob01699a.
  • Radical-Enhanced Acidity: Why Bicarbonate, Carboxyl, Hydroperoxyl, and Related Radicals Are So Acidic. J. C. Walton, J. Phys. Chem. A, 2017, 121, 7761-7767; DOI:10.1021/acs.jpca.7b08081.
  • Tethered 1,2-Si-Group Migrations in Radical-Mediated Ring Enlargements of Cyclic Alkoxysilanes: An EPR Spectroscopic and Computational Investigation. J. C. Walton, R. Kanada, T. Iwamoto, S. Shuto, H. Abe, J. Org. Chem., 2017, 82, 6886-6894; DOI: 10.1021/acs.joc.7b01011.
  • Synthetic Strategies for 5- and 6-Membered Ring Azaheterocycles Facilitated by Iminyl Radicals. J. C. Walton, Molecules, 2016, 21, 660; DOI: 10.3390/molecules21050660.
  • A Valuable Upgrade to the Portfolio of Cycloaddition Reactions. J. C. Walton, Angew. Chem. Int. Ed. 2016 , 55, 7034-7036; Angew. Chem. 2016, 128, 7148-7150; DOI: 10.1002/anie.201602891.
  • Functionalised Oximes: Emergent Precursors for Carbon-, Nitrogen- and Oxygen-Centred Radicals. J. C. Walton, Molecules, 2016, 21, 63; DOI: 10.3390/molecules21010063.
  • Bicarbonate and Alkyl Carbonate Radicals: Structural Integrity and Reactions with Lipid Components. M. Buehl, P. DaBell, D. W. Manley, R. P. McCaughan, and J. C. Walton, J. Am. Chem. Soc. 2015, 137, 16153-16162; DOI: 10.1021/jacs.5b10693.
  • Identification of Products from Canthaxanthin Oxidation. R. C. Mordi and J. C. Walton. Food Chem. 2016, 197, 836-840; doi: 10.1016/j.foodchem.2015.11.053
  • Preparative Semiconductor Photoredox Catalysis: An Emerging Theme in Organic Synthesis. D. W. Manley and J. C. Walton. Beilstein J. Org. Chem. 2015, 11, 1570-1582; doi: 10.3762/bjoc.11.173.
  • The Games Radicals Play: Special Issue on Free Radicals and Radical Ions. J. C. Walton and F. Williams, Molecules, 2015, 20, 2831-2834; DOI. 10.3390/molecules20022831
  • A Clean and Selective Radical Homocoupling Employing Carboxylic Acids with Titania Photoredox Catalysis. D. W. Manley and J. C. Walton, Org. Lett. 2014, 16, 5394-5397; DOI: 10.1021/ol502625w
  • Hydrogenations without Hydrogen: Titania Photocatalyzed Reductions of Maleimides and Aldehydes. David W. Manley, Luca Buzzetti, Andrew MacKessack-Leitch and John C. Walton. Molecules 2014, 19, 15324-15338; DOI: 10.3390/molecules190915324
  • The Importance of Chain Conformational Mobility During 5-Exo-Cyclizations of C-, N- and O-Centred Radicals. J. C. Walton. Org. Biomol. Chem. 2014, 12, 7983-7992. DOI: 10.1039/c4ob01419g
  • The Oxime Portmanteau Motif: Released Heteroradicals Undergo Incisive EPR Interrogation and Deliver Diverse Heterocycles. J. C. Walton. Acc. Chem. Res. 2014, 47, 1406-1416. DOI: org/10.1021/ar500017f.
  • Catalyst-Free Photoredox Addition-Cyclisations: Exploitation of Natural Synergy between Aryl Acetic Acids and Maleimide. D. W. Manley, A. Mills, C. O’Rourke, A. M. Z. Slawin and J. C. Walton, Chem. Eur. J. 2014, 20, 5492-5500. DOI: 10.1002/chem.201304929
  • Titania-Promoted Carboxylic Acid Alkylations of Alkenes and Cascade Addition-Cyclizations. D. W. Manley, R. T. McBurney, P. Miller, J. C. Walton, A. Mills and C. O’Rourke, J. Org. Chem. 2014, 79, 1386-1398. DOI: org/10.1021/jo4027929
  • Interplay of Ortho- with Spiro-Cyclisation During Iminyl Radical Closures onto Arenes and Heteroarenes. R. T. McBurney and J. C. Walton, Beilstein J. Org. Chem. 2013, 9, 1083-1092. DOI:10.3762/bjoc.9.120
  • Dissociation or Cyclization: Options for a Triad of Radicals Released from Oxime Carbamates. R. T. McBurney and J. C. Walton, J. Am. Chem. Soc. 2013, 135, 7349-7354. DOI: 10.1021/ja402833w
  • Rapid and selective spiro-cyclisations of O-centred radicals onto aromatic acceptors. R. T. McBurney, A. Eisenschmidt, A. M. Z. Slawin and J. C. Walton, Chem. Sci. 2013, 4, 2028-2035, DOI: 10.1039/c3sc50500f
  • An all-purpose preparation of oxime carbonates and resultant insights into the chemistry of alkoxycarbonyloxyl radicals. R. T. McBurney, A. D. Harper, A. M. Z. Slawin and John C. Walton, Chem. Sci. 2012, 3, 3436 – 3444 DOI: 10.1039/c2sc21298f
  • Unconventional titania photocatalysis: direct deployment of carboxylic acids in alkylations and annulations D. W. Manley, R. T. McBurney, P. Miller, R. F. Howe, S. Rhydderch and John C. Walton, J. Am. Chem. Soc. 2012, 134, 13580-13583. DOI: 10.1021/ja306168h
  • Microwave assisted radical organic syntheses. R. T. McBurney, F. Portela-Cubillo and J. C. Walton, RSC Adv., 2012, 2, 1264-1274. DOI: 10.1039/C1RA00909E
  • Analysis of Radicals by EPR, J. C. Walton in Encyclopedia of Radicals in Chemistry, Biology and Materials, eds. C. Chatgilialoglu and A. Studer. John Wiley & Sons Ltd, Chichester, UK, 2012, pp 147-174.
  • Electron Paramagnetic Resonance and Computational Studies of Radicals Derived from Boron-Substituted N-Heterocyclic Carbene Boranes. J. C. Walton, M. M. Brahmi, J. Monot, L. Fensterbank, M. Malacria, D. P. Curran, and E. Lacôte J. Am. Chem. Soc. 2011, 133, 10312-10321. DOI: 10.1021/ja2038485
  • UV promoted phenanthridine syntheses from oxime carbonate derived iminyl radicals. R. T. McBurney, A. M. Z. Slawin, L. A. Smart, Y. Yu and J. C. Walton, Chem. Commun. 2011, 47, 7974-7976.
  • EPR and ENDOR spectroscopic study of the reactions of aromatic azides with gallium trichloride. G. Bencivenni, R. Cesari, D. Nanni, H. El Mkami and J. C. Walton, Org. Biomol. Chem. 2010, 8, 5097-5104.
  • EPR and Pulsed ENDOR Study of Intermediates from Reactions of Aromatic Azides with Group 13 Metal Trichlorides. G. Bencivenni, R. Cesari, D. Nanni, H. El Mkami and J. C. Walton, Beilstein J. Org. Chem. 2010, 6, 713-725.
  • EPR Studies of the Generation, Structure and Reactivity of N-Heterocyclic Carbene Borane Radicals. J. C. Walton, M. M. Brahmi, L. Fensterbank, E. Lacôte, Max Malacria, Q. Chu, S.-H. Ueng, A. Solovyev and D. P. Curran, J. Am. Chem. Soc. 2010, 132, 2350-2358. DOI 10.1021/ja909502q
  • 5-Exo-Cyclizations of Pentenyliminyl Radicals: Inversion of the gem-Dimethyl Effect. F. Portela-Cubillo, R. Alonso-Ruiz, D. Sampedro and J. C. Walton, J. Phys. Chem. A 2009, 113, 10005-10012.
  • N-Heterocyclic Carbene Boryl Radicals: A New Class of Boron-Centered Radical. S.-H. Ueng, A. Solovyev, X. Yuan, S. J. Geib, L. Fensterbank, E. Lacote, M. Malacria, M. Newcomb, J. C. Walton and D. P. Curran, J. Am. Chem. Soc., 2009, 131, 11256-11262. DOI: 10.1021/ja904103x
  • Linking Borane with N-Heterocyclic Carbenes: Effective Hydrogen-Atom Donors for Radical Reactions. J. C. Walton, Angew. Chem. Int. Ed. 2009, 48, 1726-1728. DOI: 10.1002/anie.200805362
  • Microwave-promoted Syntheses of Quinazolines and Dihydroquinazolines from 2-Aminoarylalkanone O-Phenyl Oximes. Fernando Portela-Cubillo, Jackie S. Scott, and John C. Walton. J. Org. Chem. 2009, 74, 4934-4942. DOI 10.1021/jo900629g. DOI 10.1021/jo900629g
  • Thermal rearrangement of indolyl oxime esters to pyridoindoles. F. Portela-Cubillo, B. A. Surgenor, R. A. Aitken and J. C. Walton, J. Org. Chem. 2008, 73, 8124-8127; DOI: 10.1021/jo801751a
  • Dioxime oxalates; new iminyl radical precursors for syntheses of N-heterocycles. F. Portela-Cubillo, J. Lymer, E. M. Scanlan, J. S. Scott, J. C. Walton, Tetrahedron, 2008, 64, 11908-11916. DOI: 10.1016/j.tet.2008.08.112
  • From dioxime oxalates to dihydropyrroles and phenanthridines via iminyl radicals. F. Portela-Cubillo, E. M. Scanlan, J. S. Scott and J. C. Walton, Chem. Commun. 2008, 4189-4191. DOI: 10.1039/b808625g.
  • Microwave-assisted syntheses of N-heterocycles using alkenone-, alkynone- and aryl-carbonyl O-phenyl oximes: formal synthesis of neocryptolepine. F. Portela-Cubillo, J. S. Scott and J. C. Walton, J. Org. Chem. 2008, 73, 5558-5565. DOI: 10.1021/jo800847h
  • 2-(Aminoaryl)alkanone O-phenyl oximes: versatile reagents for syntheses of quinazolines. F. Portela-Cubillo, J. S. Scott and J. C. Walton, Chem. Commun. 2008, 2935-2937. DOI: 10.1039/b803630f
  • Characterisation of equatorial and axial six-membered-ring peroxyl radicals. G. A. DiLabio, K. U. Ingold and J. C. Walton, J. Org. Chem. 2007, 72, 8095-8098. DOI: 10.1021/jo7014592
  • Microwave-assisted preparations of dihydropyrroles from alkenone O-phenyl oximes. F. Portela-Cubillo, J. S. Scott, J. C. Walton, Chem. Commun. 2007, 4041-4043. DOI: 10.1039/b712582h
  • 1,4-Cyclohexadiene. J. C. Walton and F. Portela-Cubillo, Encyclopedia of Reagents for Organic Synthesis, 2007. DOI 10.1002/047084289X.rn00806.
  • Effect of chain length on radical to carbanion cyclo-coupling of bromoaryl alkyl-linked oxazolines: 1,3-areneotropic migration of oxazolines. J. C. Walton, L. J. Marshall, M. D. Roydhouse, A. M. Z. Slawin, J. Org. Chem., 2007, 72, 898-911. full text via DOI
  • Formation of a tetracyclic isoquinoline derivative by rearrangement of a [(bromophenyl)butyryl]oxazolidinone, J. C. Walton, M. D. Roydhouse, Eur. J. Org. Chem. , 2007, 1059-1063; full text via DOI
  • Radical 4-exo-cyclizations onto O-alkyloxime acceptors: towards the synthesis of penicilliin-containing antibiotics. J. C. Walton, E. M. Scanlan, Helvetica Chimica Acta , 2006, 89, 2133-2143; full text via DOI
  • Unusual radical cyclisations. J. C. Walton, Top. Curr. Chem. 2006, 264, 163-200. full text via DOI
  • Evolution of functional cyclohexadiene-based synthetic reagents: the importance of becoming aromatic. J. C. Walton and A. Studer, Acc. Chem. Res. 2005, 38, 794-802 ; full text via DOI
  • Radical-carbanion cyclo-coupling in armed aromatics: overriding steric hindrance to ring closure. M. D. Roydhouse and J. C. Walton, Chem. Commun. 2005, 4453-4455 ; full text via DOI
  • Kinetic and theoretical study of 4-exo ring closures of carbamoyl radicals onto C=C and C=N bonds. G. A. DiLabio, E. M. Scanlan and J. C. Walton, Org. Lett. 2005, 7, 155-158; full text via DOI
  • Axial and equatorial cyclohexylacyl and tetrahydropyranyl-2-acyl radicals. An experimental and theoretical study. G. A. DiLabio, K. U. Ingold, M. D. Roydhouse and J. C. Walton, Org. Lett. 2004, 6, 4319-4322.
  • O-H Bond dissociation enthalpies in oximes: order restored. D. Pratt, J. A. Blake, P. Mulder, J. C. Walton, H. -G. Korth and K. U. Ingold. J. Am. Chem. Soc. 2004, 126, 10667-10675.
  • Approach to 3-aminoindolin-2-ones via oxime ether functionalised carbamoylcyclohexadienes. A. F. Bella, A. M. Z. Slawin and J. C. Walton, J. Org. Chem. 2004, 69, 5926-5933.
  • An exploratory study of ring closures of aryl radicals onto cyclopropyl- and oxiranyl-isocyanate acceptors. By P. L. Minin and J. C. Walton, Org. Biomol. Chem. 2004, 2, 2471-2475.
  • Thermolyses of O-phenyl oxime ethers. A new source of iminyl radicals and a new source of aryloxyl radicals. By J. A. Blake, D. A. Pratt, S. Lin, J. C. Walton, P. Mulder and K. U. Ingold, J. Org. Chem. 2004, 69, 3112-3120.
  • Alkanethioimidoyl radicals: evaluation of beta-scission rates and of cyclization onto S-alkenyl substituents. By M. Minozzi, D. Nanni, and J. C. Walton. J. Org. Chem. 2004, 69, 2056-2069.
  • Preparation of beta- and gamma-lactams from carbamoyl radicals derived from oxime oxalate amides. By E. M. Scanlan, A. M. Z. Slawin and J. C. Walton, Org. Biomol. Chem. 2004, 2, 716-724.
  • Preparation of beta- and gamma-lactams via ring closures of unsaturated carbamoyl radicals derived from 1-carbamoyl-1-methylcyclohexa-2,5-dienes. By A. F. Bella, L. V. Jackson and J. C. Walton, Org. Biomol. Chem. 2004, 2, 421-428.
  • Thermal decomposition of O-benzyl ketoximes; role of reverse radical disproportionation. By J. A. Blake, K. U. Ingold, S. Lin, P. Mulder, D. A. Pratt, B. Sheeller and J. C. Walton, Org. Biomol. Chem. 2004, 2, 415-420.
  • Electron transfer induced dissociations of 2- and 4-alkyl cyclohexadienones. By A. J. McCarroll, J. A. Crayston and J. C. Walton, Tetrahedron, 2003, 59, 4275-4280.
  • Silylated cyclohexadienes as new radical chain reducing reagents: Preparative and mechanistic aspects. By A. Studer, S. Amrein, F. Schleth, T. Schulte and J. C. Walton, J. Am. Chem. Soc. 2003, 125, 5726-5733.
  • Radical ring closures of 4-isocyanato carbon-centered radicals. By P. L. Minin and J. C. Walton, J. Org. Chem. 2003, 68, 2960-2963
  • Alkenylthioimidoyl radicals: Competition between beta-scission and cyclization to dihydrothiophen-2-ylidene-amines. By M. Minozzi, D. Nanni and J. C. Walton, Org. Lett. 2003, 5, 901-904.
  • On the preparation of cyclopentadienes by a novel homolytic annulation of but-3-en-1-ones with alkynes mediated by samarium diiodide. By A. J. McCarroll and J. C. Walton, ARKIVOC 2002, 55-62; www.arkat-usa.org/ark/journal/2002/Lloyd/lloyd-index.htm.
  • Preparation of 1-phenylcyclohexa-2,5-diene-1-carboxylates and their use in free-radical mediated syntheses. By P. A. Baguley, L. V. Jackson and J. C. Walton, J. Chem. Soc., Perkin Trans. 1, 2002, 304-309.
  • Organic syntheses through free-radical annulations and related cascade sequences. By A. J. McCarroll and J. C. Walton, J. Chem. Soc., Perkin Trans. 1, 2001, 3215-3229.
  • Homolytic dissociation of 1-substituted cyclohexa-2,5-diene-1-carboxylic acids: an EPR spectroscopic study of chain propagation. By L. V. Jackson and J. C. Walton, J. Chem.Soc., Perkin Trans. 2, 2001, 1758-1764.
  • Programming organic molecules: design and management of organic syntheses through free-radical cascade processes. By A. J. McCarroll and J. C. Walton, Angew. Chem. 2001, 113, 2282-2307; Int. Ed. 2001, 40, 2224-2248.
  • Inhibition of human platelet aggregation by a novel S-nitrosothiol is abolished by haemoglobin and red blood cells in vitro: implications for anti-thrombotic therapy. By I. L. Megson, N. Sogo, F. A. Mazzei, A. R. Butler, J. C. Walton and D. J. Webb. Brit. J. Pharm. 2000, 131, 1391-1398.
  • Generation of aminoacyl radicals from 1-carbamoyl-1-methylcyclohexa-2,5-dienes: a new tin-free homolytic route to b- and g-lactams. By L. V. Jackson and J. C. Walton, Chem. Commun. 2000, 2327-2328.
  • Conceptual and synthetic strategies for the preparation of organic magnets. By J. A. Crayston, J. N. Devine and J. C. Walton, Tetrahedron, 2000, 56, 7829-7857.
  • Exploitation of aldoxime esters as radical precursors in preparative and EPR spectroscopic roles. By A. J. McCarroll and J. C. Walton, J. Chem. Soc., Perkin Trans. 2. 2000, 2399-2409.
  • Photolytic and radical induced decompositions of O-alkyl aldoxime ethers. By A. J. McCarroll and J. C. Walton, J. Chem. Soc., Perkin Trans. 2, 2000, 1868-1875.
  • The influence of boryl substituents on the formation and reactivity of adjacent and vicinal free radical centers. By J. C. Walton, A. J. McCarroll, Q. Chen, B. Carboni and R. Nziengui, J. Am. Chem. Soc. 2000, 122, 5455-5463.
  • Aberrant SRN1 reaction of 4-aminophenol with a,p-dinitrocumene: EPR observation of intermediates. By R. G. Scamehorn, L. A. Mahnke, R. D. Krause, B. L. Frey, D. L. Hendriksen, K. S. Jahn, S. G. Kultgen and J. C. Walton, Org. Lett. 2000, 2, 827-829.
  • Enhanced radical delivery from aldoxime esters for EPR and ring closure applications. By A. J. McCarroll and J. C. Walton, Chem. Commun. 2000, 351-352.
  • Flight from the tyranny of tin: the quest for practical radical sources free from metal encumbrances. By P. A. Baguley and J. C. Walton, Angew. Chem. Int. Ed. Engl. 1998, 37 , 3073-3082.

    Map of North Radicalia

    From: Angew. Chem. 1998, 110, 3273-3283; Int. Ed. Engl. 1998, 37, 3073-3082. Angew. Chem. Home Page.

  • Thermal and induced decompositions of N-alkoxycarbonyldihydropyridines: end product analysis and EPR spectra of azacyclohexadienyl radicals. By P. A. Baguley and J. C. Walton J. Chem. Soc. Perkin Trans. 2 1998, 1423-1429
  • Reductive free-radical alkylations and cyclisations mediated by 1-alkylcyclohexa-2,5-dinene-1-carboxylic acids. By P. A. Baguley and J. C. Walton, J. Chem. Soc., Perkin Trans. 1 , 1998, 2073-2082.
  • 1- and 2-Adamantyl Radicals and Cations in the Gas Phase: Thermochemistry and Mass Spectrometry. By C. Aubry, J. L. Holmes and J. C. Walton, J. Phys. Chem. A, 1998, 102, 1389-1393.
  • Homolytic Substitution: A Molecular Ménage à Trois. By J. C. Walton, Acc. Chem. Res., 1998, 31, 99-107.
  • Covalent Binding of Redox Active Centres to Preformed Regioregular Polythiophenes. By A. Iraqi, J. A. Crayston and J. C. Walton, J. Mater. Chem., 1998, 8, 31-36.
  • Exploratory Study of Diazoketones as Spin Traps for Nitric Oxide. By J. C. Walton and J. S. B. Park, J. Chem. Soc., Perkin Trans. 2, 1997, 2585-3588.
  • Reactions of Nitric Oxide and Nitrogen Dioxide with Functionalised Alkenes and Dienes. By J. S. B. Park and J. C. Walton, J. Chem. Soc., Perkin Trans. 2, 1997, 2579-2583.
  • First EPR Characterisation of the Structures and Reactivities of alpha- and beta-Boryl Radicals Derived from Boronic Esters. By A. McCarroll, J. C. Walton, R. Nziengui and B. Carboni, Chem. Commun., 1997, 2075-2076.
  • Organic Radicals. By J. C. Walton, in “Espectroscopia de Resonancia Paramagnetica Electronica” ed. T. Rojo, L. Lezama and J. M. Barandiarán, Servicio Editorial Universidad del Pais Vasco, 1997, pp 253-283.
  • Functionalsiation of Poly(p-phenylenevinylene) Polymers with Pendant Nitroxide Groups. By A. Iraqi, A. Mlynski, A. Heard, J. C. Walton and J. A. Crayston, Synthetic Metals, 1997, 84, 333-334.
  • Alkyl Radical Generation Using Cyclohexa-1,4-diene-3-carboxylates and 2,5-Dihydrofuran-2-carboxylates. By G. Binmore, J. C. Walton and L. Cardellini, J. Chem. Soc., Perkin Trans. 2, 1997, 757-762.
  • Cyclopropylmethyl Radical to But-3-enyl Radical Rearrangements. By J. C. Walton, in “Carbocyclic Three- and Four-Membered Ring Compounds”, Vol. E 17c, Section 2.4.1.5.2, of Houben Weyl, Methoden der Organischen Chemie, ed. A. de Meijere, Georg Thieme Verlag, Stuttgart, 1996, pp 2438-2525.
  • Bicyclo[1.1.1]pent-1-yl: A Tertiary Alkyl Radical with Enhanced Reactivity, By J. T. Banks, K. U. Ingold, E. W. Della, and J. C. Walton, Tetrahedron Lett., 1996, 37, 8059-8060.
  • Oxidation of Retinyl Acetate and Analogues by Nitric Oxide and Nitrogen Dioxide. By M. Afzal and J. C. Walton, Bioorg. Med. Chem. Lett., 1996, 6, 2329-2332.
  • Unique Carbon-Carbon Bond Homolysis in 3-Alkylcyclohexa-1,4-dienyl-3-carboxylic Acid Radicals. By P. A. Baguley, G. Binmore, A. Milne and J. C. Walton, Chem. Commun., 1996, 2199-2200.
  • EPR Study of Bridgehead-Substituted Bicyclo[2.2.2]oct-1-yl and Triptycycl Radicals. By G. T. Binmore, J. C. Walton, W. Adcock, C. I. Clark and A. R. Krstic, Magn. Reson. Chem., 1995, 33, S53-S59.
  • Synthesis, Spectroelectrochemistry and Thermochromism of Regioregular Head-to-tail Oligo- and Poly-[3-aryloxyhexylthiophenes]. By A. Iraqi, J. A. Crayston and J. C. Walton, J. Mater. Chem., 1995, 5, 1831-1836.
  • Cross Cage Interactions in Substituted Bicyclo[1.1.1]pent-1-yl Radicals. Dissociation to [1.1.1]Propellane. By W. Adcock, G. T. Binmore, A. R. Krstic, J. C. Walton and J. Wilkie, J. Am. Chem. Soc., 1995, 117, 2758-2766.
  • Radical-chain Decomposition of Cyclohexa-1,4-diene-3-carboxylates and 2,5-Dihydrofuran-2-carboxylates. By G. Binmore, J. C. Walton and L. Cardellini, J. Chem. Soc., Chem. Commun., 1995, 27-28.
  • An E.P.R. and Kinetic Investigation of Tricyclo[3.1.1.03,6]hept-6-yl and Tricyclo[3.1.1.03,6]hept-6-ylmethyl Radicals. By G. T. Binmore, E. W. Della, W. K. Janowski, P. Mallon and J. C.Walton, Aust. J. Chem., 1994, 47, 1285-1293.
  • Homolytic Reactions of Homocubane and Basketane: Rearrangement of the 9-Basketyl Radical by Multiple b-Scissions. By G. T. Binmore, E. W. Della, G. M. Elsey, N. J. Head and J. C. Walton, J. Am. Chem. Soc., 1994, 116, 2759-2766.

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